You can request Exeter or Bristol Airport from Plymouth. Both journeys need time on the road, so allow for that before deciding when you want the driver to collect you.
For Plymouth, the listed pickup areas include Plympton, Plymstock, Saltash, Ivybridge, Tavistock, Yelverton and surrounding Plymouth areas. When booking, use the address where you will actually be waiting.
For a long airport journey from Plymouth, leave time for the drive and check-in. Check the date for overnight travel and choose a vehicle with enough space for every bag.
For travel beyond Plymouth, you can request a direct journey to a UK hotel, city or event. Think about your luggage for the whole visit when choosing the vehicle.